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Issue 26, 2019
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Photoluminescent Cu(i) vs. Ag(i) complexes: slowing down emission in Cu(i) complexes by pentacoordinate low-lying excited states

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Abstract

This work describes the synthesis, and structural, spectroscopic, and theoretical studies of a mononuclear silver(I) complex with the formula [Ag(Xantphos)(4,4′-(MeO)2-2,2′-bipy)]BF4·DCM (1·BF4) [Xantphos: 4,5-bis(diphenylphosphino)-9,9′-dimethylxanthene]. We provide meaningful insights into the enhancement of the photoluminescence features of this silver(I) complex compared to its copper(I) analogue.

Graphical abstract: Photoluminescent Cu(i) vs. Ag(i) complexes: slowing down emission in Cu(i) complexes by pentacoordinate low-lying excited states

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Publication details

The article was received on 20 Feb 2019, accepted on 04 Apr 2019 and first published on 23 Apr 2019


Article type: Paper
DOI: 10.1039/C9DT00772E
Dalton Trans., 2019,48, 9765-9775

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    Photoluminescent Cu(I) vs. Ag(I) complexes: slowing down emission in Cu(I) complexes by pentacoordinate low-lying excited states

    J. M. Carbonell-Vilar, E. Fresta, D. Armentano, R. D. Costa, M. Viciano-Chumillas and J. Cano, Dalton Trans., 2019, 48, 9765
    DOI: 10.1039/C9DT00772E

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