Issue 13, 2019

Salen supported Al–O–C[triple bond, length as m-dash]P and Ga–P[double bond, length as m-dash]C[double bond, length as m-dash]O complexes

Abstract

The first OCP adducts of aluminium and gallium are reported. The complexes are supported by sterically encumbered salen ligands and reveal a selective binding to O and P, respectively. Their reactivity with diazaphosphenium Lewis acids and N-heterocyclic carbene Lewis bases is described, in addition to cycloaddition reactions with s-tetrazines.

Graphical abstract: Salen supported Al–O–C [[triple bond, length as m-dash]] P and Ga–P [[double bond, length as m-dash]] C [[double bond, length as m-dash]] O complexes

Supplementary files

Article information

Article type
Paper
Submitted
31 Jan 2019
Accepted
01 Mar 2019
First published
12 Mar 2019
This article is Open Access
Creative Commons BY-NC license

Dalton Trans., 2019,48, 4370-4374

Salen supported Al–O–C[triple bond, length as m-dash]P and Ga–P[double bond, length as m-dash]C[double bond, length as m-dash]O complexes

Y. Mei, J. E. Borger, D. Wu and H. Grützmacher, Dalton Trans., 2019, 48, 4370 DOI: 10.1039/C9DT00485H

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