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Issue 21, 2019
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Metallopolymers cross-linked with self-assembled Ln4L4 cages

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Herein, we fabricated a hybrid PDVB-Ln4L4 metallopolymer using a vinyl functionalized lanthanide-organic tetrahedral cage as the cross-linking agent. Such a covalent embedding strategy not only tunes the morphology and porosity of the metallopolymer, but also improves the luminescence property of the lanthanide organic polyhedron. Potential application in lanthanide separation has also been demonstrated. This study provides a potential strategy for the immobilization of multinuclear lanthanide-organic edifices toward heterogeneous application.

Graphical abstract: Metallopolymers cross-linked with self-assembled Ln4L4 cages

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Article information

20 Dec 2018
22 Feb 2019
First published
23 Feb 2019

Dalton Trans., 2019,48, 7080-7084
Article type

Metallopolymers cross-linked with self-assembled Ln4L4 cages

Q. Yan, L. Zhou, H. Zhou, Z. Wang, L. Cai, X. Guo, X. Sun and Q. Sun, Dalton Trans., 2019, 48, 7080
DOI: 10.1039/C8DT05015E

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