Jump to main content
Jump to site search

Issue 11, 2019
Previous Article Next Article

Redox chemistry of an anionic dithiolene radical

Author affiliations

Abstract

The redox chemistry of the first stable anionic dithiolene radical was investigated by both reactivity and cyclic voltammetry studies. While one-electron reduction of by Cp2Co or KC8 affords the corresponding dithiolate dimers 2 and 3, respectively, one-electron oxidation of by Ph3C+BF4 (or O2) conveniently gives 4, the neutral dithiolene dimer.

Graphical abstract: Redox chemistry of an anionic dithiolene radical

Back to tab navigation

Supplementary files

Article information


Submitted
18 Dec 2018
Accepted
07 Feb 2019
First published
07 Feb 2019

Dalton Trans., 2019,48, 3543-3546
Article type
Communication
Author version available

Redox chemistry of an anionic dithiolene radical

Y. Wang, Y. Xie, P. Wei, H. F. Schaefer and G. H. Robinson, Dalton Trans., 2019, 48, 3543
DOI: 10.1039/C8DT04989K

Social activity

Search articles by author

Spotlight

Advertisements