Issue 1, 2019
From the journal:

Dalton Transactions

Synthesis and ligand substitution reactions of κ4-B,S,S′,S′′-ruthenaboratranes†

Mark R. St.-J. Foreman, ORCID logo a   Anthony F. Hill, ORCID logo *b   Chenxi Ma,b   Never Tshabangbc  and  Andrew J. P. Whited  

* Corresponding authors

a Department of Chemistry and Chemical Engineering, Nuclear Chemistry and Industrial Materials Recycling, Chalmers University of Technology, Göteborg, Sweden

b Research School of Chemistry, Australian National University, Acton, Canberra, A.C.T., Australia
E-mail: a.hill@anu.edu.au

c Department of Chemistry, University of Botswana, Gaborone, Botswana

d Chemical Crystallography Laboratory, Department of Chemistry, Imperial College London White City Campus, UK

Abstract

A range of ruthenaboratranes of the form [Ru(CO)L{κ4-B,S,S′,S′′-B(mt)3}] (mt = N-methylmercaptoimidazolyl) have been prepared either by substitution of the PPh3 ligand in [Ru(CO)(PPh3){κ4-B,S,S′,S′′-B(mt)3}] by L (L = PMe2Ph, PMe3, P(OMe)3, P(OEt)3, P(OPh)3) or reactions of [RuCl(R)(CO)Ln] (R = Ph, CH[double bond, length as m-dash]CHPh; n = 2, L = PCy3; n = 3, L = P(OMe)3, PMe2Ph) with Na[HB(mt)3].

Graphical abstract: Synthesis and ligand substitution reactions of κ4-B,S,S′,S′′-ruthenaboratranes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C8DT04278K
Article type
Paper
Submitted
26 Oct 2018
Accepted
23 Nov 2018
First published
26 Nov 2018

Dalton Trans., 2019,48, 209-219

Permissions

Request permissions

Synthesis and ligand substitution reactions of κ4-B,S,S′,S′′-ruthenaboratranes

M. R. St.-J. Foreman, A. F. Hill, C. Ma, N. Tshabang and A. J. P. White, Dalton Trans., 2019, 48, 209 DOI: 10.1039/C8DT04278K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements