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Issue 41, 2018
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Selective formation of a two-dimensional coordination polymer based on a tridentate phospholane ligand and gold(I)

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Abstract

The tridentate phosphine ligand 1,3,5-tris[(E)-(4-phospholano-2,6-diethyl)styryl]benzene (1) reacts with [AuCl(tht)] (tht = tetrahydrothiophene) independent of the stoichiometry employed with selective formation of a two-dimensional coordination polymer (ratio 1 : 1) with the gold(I) cations in a trigonal-planar [3 + 1] coordination geometry. Each of the three coordinating phosphine units originates from another ligand, thus forming a polymeric structure.

Graphical abstract: Selective formation of a two-dimensional coordination polymer based on a tridentate phospholane ligand and gold(i)

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Publication details

The article was received on 07 Sep 2018, accepted on 10 Sep 2018 and first published on 11 Sep 2018


Article type: Paper
DOI: 10.1039/C8DT03630F
Citation: Dalton Trans., 2018,47, 14515-14520

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    Selective formation of a two-dimensional coordination polymer based on a tridentate phospholane ligand and gold(I)

    R. Hoy, P. Lönnecke and E. Hey-Hawkins, Dalton Trans., 2018, 47, 14515
    DOI: 10.1039/C8DT03630F

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