Issue 45, 2018

Insights into the influence of ethylene group orientation on the iron(iii) spin state in the spin crossover complex [FeIII(Sal2-trien)]+

Abstract

The DFT calculations of the spin crossover complex [FeIII(Sal2-trien)]+ (1) with the following classification of conformers of 1 were performed. The study shows that rearrangements of ethylene group orientation in a coordinated ligand lead to the stabilization of the high-spin or low-spin iron(III) state.

Graphical abstract: Insights into the influence of ethylene group orientation on the iron(iii) spin state in the spin crossover complex [FeIII(Sal2-trien)]+

Supplementary files

Article information

Article type
Communication
Submitted
07 Sep 2018
Accepted
19 Oct 2018
First published
22 Oct 2018

Dalton Trans., 2018,47, 16040-16043

Insights into the influence of ethylene group orientation on the iron(III) spin state in the spin crossover complex [FeIII(Sal2-trien)]+

M. A. Blagov, V. B. Krapivin, S. V. Simonov and N. G. Spitsyna, Dalton Trans., 2018, 47, 16040 DOI: 10.1039/C8DT03619E

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