Issue 37, 2018
From the journal:

Dalton Transactions

Dehydropolymerisation of methylamine borane using a dinuclear 1,3-allenediyl bridged zirconocene complex†

M. Trose,a   M. Reiß,a   F. Reiß, ORCID logo *a   F. Anke,a   A. Spannenberg,a   S. Boye,b   A. Lederer, ORCID logo bc   P. Arndta  and  T. Beweries ORCID logo *a  

* Corresponding authors

a Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock, Germany
E-mail: fabian.reiss@catalysis.de, torsten.beweries@catalysis.de

b Leibniz-Institut für Polymerforschung Dresden, Hohe Str. 6, 01069 Dresden, Germany

c Technische Universität Dresden, 01062 Dresden, Germany

Abstract

The dinuclear zirconocene chloride complex 1 is a highly active precatalyst for the dehydropolymerisation of methylamine borane. Comparison with mononuclear Zr chlorides and related dinuclear complexes suggests that the nature of the bridging motif is essential for the unique reactivity of 1.

Graphical abstract: Dehydropolymerisation of methylamine borane using a dinuclear 1,3-allenediyl bridged zirconocene complex

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C8DT03311K
Article type
Communication
Submitted
13 Aug 2018
Accepted
20 Aug 2018
First published
21 Aug 2018

Dalton Trans., 2018,47, 12858-12862

Permissions

Request permissions

Dehydropolymerisation of methylamine borane using a dinuclear 1,3-allenediyl bridged zirconocene complex

M. Trose, M. Reiß, F. Reiß, F. Anke, A. Spannenberg, S. Boye, A. Lederer, P. Arndt and T. Beweries, Dalton Trans., 2018, 47, 12858 DOI: 10.1039/C8DT03311K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements