Issue 37, 2018

Dehydropolymerisation of methylamine borane using a dinuclear 1,3-allenediyl bridged zirconocene complex

Abstract

The dinuclear zirconocene chloride complex 1 is a highly active precatalyst for the dehydropolymerisation of methylamine borane. Comparison with mononuclear Zr chlorides and related dinuclear complexes suggests that the nature of the bridging motif is essential for the unique reactivity of 1.

Graphical abstract: Dehydropolymerisation of methylamine borane using a dinuclear 1,3-allenediyl bridged zirconocene complex

Supplementary files

Article information

Article type
Communication
Submitted
13 Aug 2018
Accepted
20 Aug 2018
First published
21 Aug 2018

Dalton Trans., 2018,47, 12858-12862

Dehydropolymerisation of methylamine borane using a dinuclear 1,3-allenediyl bridged zirconocene complex

M. Trose, M. Reiß, F. Reiß, F. Anke, A. Spannenberg, S. Boye, A. Lederer, P. Arndt and T. Beweries, Dalton Trans., 2018, 47, 12858 DOI: 10.1039/C8DT03311K

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