Issue 45, 2018

A luminescent dicyanidonitridotechnetium(v) core with tridentate ligand coordination sites

Abstract

A novel, luminescent technetium complex, [TcN(CN)2bpa] (bpa = bis-(2-pyridylmethyl)amine), with tridentate ligand coordination sites was synthesized and characterized. Photoemission with a maximum wavelength at 666 nm was observed in the solid-state at 296 K.

Graphical abstract: A luminescent dicyanidonitridotechnetium(v) core with tridentate ligand coordination sites

Supplementary files

Article information

Article type
Communication
Submitted
19 Jul 2018
Accepted
21 Sep 2018
First published
27 Sep 2018

Dalton Trans., 2018,47, 16027-16030

A luminescent dicyanidonitridotechnetium(V) core with tridentate ligand coordination sites

T. Yoshimura, K. Nagata, T. Shiroyama, Y. Kino, T. Takayama, T. Sekine and A. Shinohara, Dalton Trans., 2018, 47, 16027 DOI: 10.1039/C8DT02935K

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