Issue 35, 2018

Two- and three-dimensional hybrid zinc phosphites: syntheses, structures and photoluminescence properties

Abstract

Two zinc-phosphites modified by a rigid amine 3,5-bis(imidazole-1-yl)pyridine (BIP), [Zn2(HPO3)2(BIP)]·H2O (1) and [Zn3(HPO3)3(BIP)(H2O)]·H2O (2), were solvothermally prepared. Compound 1 possesses a zincophosphite layer decorated by BIP moieties via coordinating to intralayer Zn(II) ions. Compound 2 features a 3D frame with a pillar-layer structure, in which the organic BIP pillars the inorganic zincophosphite layer via coordinating to interlayer Zn(II) ions. The structural diversity from a 2D layer to a 3D frame was mainly attributable to the different bridging modes of BIP in the process of assembly. Their temperature-dependent photoluminescence properties have also been studied.

Graphical abstract: Two- and three-dimensional hybrid zinc phosphites: syntheses, structures and photoluminescence properties

Supplementary files

Article information

Article type
Paper
Submitted
06 Jul 2018
Accepted
15 Aug 2018
First published
16 Aug 2018

Dalton Trans., 2018,47, 12468-12473

Two- and three-dimensional hybrid zinc phosphites: syntheses, structures and photoluminescence properties

S. Han, X. Zhang, J. Pan, Y. Mu, J. Li and G. Wang, Dalton Trans., 2018, 47, 12468 DOI: 10.1039/C8DT02761G

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