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Issue 37, 2018
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[Ln16] complexes (Ln = GdIII, DyIII): molecular analogues of natural minerals such as hydrotalcite

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Abstract

Two new hexadecanuclear lanthanide complexes employing the 1,5-bis(salicylidene)carbohydrazide (H2bsc) ligand are reported herein. These polynuclear aggregates crystallize in the R[3 with combining macron] space group, which is unprecedented in a family of lanthanide complexes with such high nuclearity. Magnetic susceptibility measurements reveal weak intramolecular interactions between the magnetic centres, and in the case of compound 2 (DyIII), single-molecule magnet properties are observed.

Graphical abstract: [Ln16] complexes (Ln = GdIII, DyIII): molecular analogues of natural minerals such as hydrotalcite

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Article information


Submitted
26 Jun 2018
Accepted
17 Aug 2018
First published
20 Aug 2018

Dalton Trans., 2018,47, 12847-12851
Article type
Communication

[Ln16] complexes (Ln = GdIII, DyIII): molecular analogues of natural minerals such as hydrotalcite

P. Richardson, T. Hsu, C. Kuo, R. J. Holmberg, B. Gabidullin, M. Rouzières, R. Clérac, M. Murugesu and P. Lin, Dalton Trans., 2018, 47, 12847
DOI: 10.1039/C8DT02609B

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