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Issue 32, 2018
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Methyl camouflage in the ten-vertex closo-dicarbaborane(10) series. Isolation of closo-1,6-R2C2B8Me8 (R = H and Me) and their monosubstituted analogues

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Abstract

Reported are procedures leading to the first types of methyl camouflaged dicarbadecaboranes with fewer than eleven vertices. The compounds contain the closo-1,6-C2B8 scaffolding inside the egg-shaped hepta – decamethyl sheath, which imparts unusually high air and solvolytic stability to all of these compounds.

Graphical abstract: Methyl camouflage in the ten-vertex closo-dicarbaborane(10) series. Isolation of closo-1,6-R2C2B8Me8 (R = H and Me) and their monosubstituted analogues

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Publication details

The article was received on 25 Jun 2018, accepted on 17 Jul 2018 and first published on 23 Jul 2018


Article type: Paper
DOI: 10.1039/C8DT02586J
Citation: Dalton Trans., 2018,47, 11070-11076
  • Open access: Creative Commons BY-NC license
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    Methyl camouflage in the ten-vertex closo-dicarbaborane(10) series. Isolation of closo-1,6-R2C2B8Me8 (R = H and Me) and their monosubstituted analogues

    M. Bakardjiev, O. L. Tok, A. Růžička, Z. Růžičková, J. Holub, D. Hnyk, Z. Špalt, J. Fanfrlík and B. Štíbr, Dalton Trans., 2018, 47, 11070
    DOI: 10.1039/C8DT02586J

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