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Issue 33, 2018
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Development of catalytic nitrogen fixation using transition metal–dinitrogen complexes under mild reaction conditions

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Abstract

This paper describes our recent progress in catalytic nitrogen fixation using transition metal–dinitrogen complexes as catalysts. Our research group has recently developed novel reaction systems for the catalytic transformation of molecular dinitrogen into ammonia and hydrazine using molybdenum–, iron–, cobalt– and vanadium–dinitrogen complexes under mild reaction conditions. The new findings presented in this paper may provide a new approach to the development of economical nitrogen fixation to replace the energy-consuming Haber–Bosch process.

Graphical abstract: Development of catalytic nitrogen fixation using transition metal–dinitrogen complexes under mild reaction conditions

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Article information


Submitted
24 Jun 2018
Accepted
26 Jul 2018
First published
26 Jul 2018

Dalton Trans., 2018,47, 11290-11297
Article type
Perspective
Author version available

Development of catalytic nitrogen fixation using transition metal–dinitrogen complexes under mild reaction conditions

Y. Nishibayashi, Dalton Trans., 2018, 47, 11290
DOI: 10.1039/C8DT02572J

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