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Issue 33, 2018
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Structural snapshots of the rearrangement of the bis(di-tert-butyl-aminophenyl)amine pincer ligand in the presence of transition metal ions

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Abstract

The bis(di-tert-butyl-aminophenyl)amine ligand H3LN,N,N was reacted with Mn(II), Co(II), Fe(III) and Cu(II) salts in air. The ligand undergoes oxidative transformations, which involve intra and intermolecular C–N and N–N bond formations. A rare aromatic C–N bond cleavage leading to a C–O bond has also been observed.

Graphical abstract: Structural snapshots of the rearrangement of the bis(di-tert-butyl-aminophenyl)amine pincer ligand in the presence of transition metal ions

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Article information


Submitted
15 Jun 2018
Accepted
09 Jul 2018
First published
16 Jul 2018

Dalton Trans., 2018,47, 11303-11307
Article type
Communication

Structural snapshots of the rearrangement of the bis(di-tert-butyl-aminophenyl)amine pincer ligand in the presence of transition metal ions

N. Leconte, B. Baptiste, C. Philouze and F. Thomas, Dalton Trans., 2018, 47, 11303
DOI: 10.1039/C8DT02462F

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