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Issue 41, 2018
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Direct observation of Mg2+ complexes in ionic liquid solutions by 31Mg β-NMR spectroscopy

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Abstract

NMR spectra of Mg2+ ions in ionic liquids were recorded using a highly sensitive variant of NMR spectroscopy known as β-NMR. The β-NMR spectra of MgCl2 in EMIM-Ac and EMIM-DCA compare favourably with conventional NMR, and exhibit linewidths of ∼3 ppm, allowing for discrimination of species with oxygen and nitrogen coordination.

Graphical abstract: Direct observation of Mg2+ complexes in ionic liquid solutions by 31Mg β-NMR spectroscopy

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Publication details

The article was received on 07 Jun 2018, accepted on 12 Sep 2018 and first published on 03 Oct 2018


Article type: Communication
DOI: 10.1039/C8DT02350F
Citation: Dalton Trans., 2018,47, 14431-14435
  • Open access: Creative Commons BY-NC license
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    Direct observation of Mg2+ complexes in ionic liquid solutions by 31Mg β-NMR spectroscopy

    D. Szunyogh, R. M. L. McFadden, V. L. Karner, A. Chatzichristos, T. Day Goodacre, M. H. Dehn, L. Formenti, D. Fujimoto, A. Gottberg, E. Kallenberg, I. Kálomista, R. F. Kiefl, F. H. Larsen, J. Lassen, C. D. P. Levy, R. Li, W. A. MacFarlane, I. McKenzie, G. D. Morris, S. Pallada, M. R. Pearson, S. P. A. Sauer, P. Schaffer, P. W. Thulstrup, L. Hemmingsen and M. Stachura, Dalton Trans., 2018, 47, 14431
    DOI: 10.1039/C8DT02350F

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