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Issue 27, 2018
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Pseudotetrahedral cobalt(ii) complexes with PNP-ligands showing uniaxial magnetic anisotropy

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Abstract

Two mononuclear pseudotetrahedral cobalt(II) complexes with the formula Co(PNP)X2, where X = Cl (1) or X = SCN (2) and PNP = bis(2-(diphenylphosphaneyl)-4-methylphenyl)amine, have been synthesised. Magnetic and high-frequency/field electron paramagnetic resonance (HF-EPR) spectroscopy and ab initio calculation studies reveal that both complexes show uniaxial magnetic anisotropy.

Graphical abstract: Pseudotetrahedral cobalt(ii) complexes with PNP-ligands showing uniaxial magnetic anisotropy

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Article information


Submitted
27 Apr 2018
Accepted
05 Jun 2018
First published
06 Jun 2018

Dalton Trans., 2018,47, 8874-8878
Article type
Communication

Pseudotetrahedral cobalt(II) complexes with PNP-ligands showing uniaxial magnetic anisotropy

Y. Zhai, Y. Deng and Y. Zheng, Dalton Trans., 2018, 47, 8874
DOI: 10.1039/C8DT01683F

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