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Issue 31, 2018
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Chiral Cu(ii), Co(ii) and Ni(ii) complexes based on 2,2′-bipyridine modified peptoids

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Abstract

Helical peptoids bearing 2,2′-bipyridine, varied in their chiral bulky side chains and their N-terminus form complexes with Cu(II), Co(II) and Ni(II) via intramolecular binding. Chiral induction from the peptoid to each metal center could be only observed in some cases and is dependent on the identity of the N-terminus and on its position relative to the metal center.

Graphical abstract: Chiral Cu(ii), Co(ii) and Ni(ii) complexes based on 2,2′-bipyridine modified peptoids

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Supplementary files

Article information


Submitted
04 Apr 2018
Accepted
01 Jul 2018
First published
02 Jul 2018

Dalton Trans., 2018,47, 10767-10774
Article type
Paper

Chiral Cu(II), Co(II) and Ni(II) complexes based on 2,2′-bipyridine modified peptoids

M. Baskin and G. Maayan, Dalton Trans., 2018, 47, 10767 DOI: 10.1039/C8DT01308J

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