Issue 13, 2018
From the journal:

Dalton Transactions

Through-conjugation of two phosphaalkyne (‘C[triple bond, length as m-dash]P’) moieties mediated by a bimetallic scaffold †

Matthew. C. Leech ORCID logo a  and  Ian R. Crossley ORCID logo *a  

* Corresponding authors

a Department of Chemistry, University of Sussex, Brighton, UK
E-mail: i.crossley@sussex.ac.uk
Fax: +44 (0)1273876678
Tel: +44 (0)1273 877302

Abstract

Through-conjugation of two phosphaalkyne moieties within an isolable molecule is demonstrated for the first time with the synthesis of [{Ru(dppe)2}2{μ-(C[triple bond, length as m-dash]C)2C6H4-p}(C[triple bond, length as m-dash]P)2], via base-induced desilylation of [{Ru(dppe)2}2{μ-(C[triple bond, length as m-dash]C)2C6H4-p}(η1-P[triple bond, length as m-dash]CSiMe3)2]2+. The nature of the cyaphide ligands and their influence upon the bimetallic core are studied electrochemically.

Graphical abstract: Through-conjugation of two phosphaalkyne (‘C [[triple bond, length as m-dash]] P’) moieties mediated by a bimetallic scaffold

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Article information

DOI
https://doi.org/10.1039/C8DT00110C
Article type
Communication
Submitted
10 Jan 2018
Accepted
06 Feb 2018
First published
28 Feb 2018
This article is Open Access
Creative Commons BY license

Dalton Trans., 2018,47, 4428-4432

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Through-conjugation of two phosphaalkyne (‘C[triple bond, length as m-dash]P’) moieties mediated by a bimetallic scaffold

Matthew. C. Leech and I. R. Crossley, Dalton Trans., 2018, 47, 4428 DOI: 10.1039/C8DT00110C

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