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Issue 8, 2018

Bromine-rich complexes of bismuth: experimental and theoretical studies

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Abstract

Three novel polybromide complexes of bismuth(III) – (2,6-MePyH)3[BiBr5(Br3)] (1), (H2bpp){[BiBr5](Br2)} (2) and (3-ClPyH)2{[BiBr5](Br2)} (3) – were synthesized. The results of an extended screening involving a set of organic cations resulting in the formation/non-formation of Bi(III) polybromides are presented and discussed. The nature of Br⋯Br interactions in Bi(III) polybromides was investigated by theoretical methods, enabling the estimation of their energies.

Graphical abstract: Bromine-rich complexes of bismuth: experimental and theoretical studies

Supplementary files

Article information


Submitted
19 Dec 2017
Accepted
21 Jan 2018
First published
22 Jan 2018

Dalton Trans., 2018,47, 2683-2689
Article type
Paper

Bromine-rich complexes of bismuth: experimental and theoretical studies

S. A. Adonin, I. D. Gorokh, A. S. Novikov, D. G. Samsonenko, P. E. Plyusnin, M. N. Sokolov and V. P. Fedin, Dalton Trans., 2018, 47, 2683 DOI: 10.1039/C7DT04779G

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