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Issue 4, 2018

Preparation and reactivity of iron complexes bearing anionic carbazole-based PNP-type pincer ligands toward catalytic nitrogen fixation

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Abstract

Iron–chloride, –dinitrogen, and –methyl complexes bearing anionic carbazole-based PNP-type pincer ligands are designed, prepared and characterized by X-ray analysis. Some iron complexes are found to work as catalysts toward nitrogen fixation under mild reaction conditions.

Graphical abstract: Preparation and reactivity of iron complexes bearing anionic carbazole-based PNP-type pincer ligands toward catalytic nitrogen fixation

Supplementary files

Article information


Submitted
16 Nov 2017
Accepted
05 Dec 2017
First published
06 Dec 2017

Dalton Trans., 2018,47, 1117-1121
Article type
Paper

Preparation and reactivity of iron complexes bearing anionic carbazole-based PNP-type pincer ligands toward catalytic nitrogen fixation

J. Higuchi, S. Kuriyama, A. Eizawa, K. Arashiba, K. Nakajima and Y. Nishibayashi, Dalton Trans., 2018, 47, 1117 DOI: 10.1039/C7DT04327A

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