Issue 3, 2018

Exploration of new water stable proton-conducting materials in an amino acid-templated metal phosphate system

Abstract

Two new metal phosphates, namely, Zn(HPO4)(DL-C3H7NO2) (SCU-4) and In(HPO4)(H2PO4)(DL-C3H7NO2) (SCU-12), were prepared in the presence of the amino acid L-alanine. SCU-4 has a ladderlike structure with edge-sharing 4-rings. SCU-12 represents the first example of a three-dimensional metal phosphate templated by an amino acid. It remains stable in boiling water and shows a high proton conductivity at room temperature under 98% relative humidity.

Graphical abstract: Exploration of new water stable proton-conducting materials in an amino acid-templated metal phosphate system

Supplementary files

Article information

Article type
Communication
Submitted
02 Nov 2017
Accepted
28 Nov 2017
First published
30 Nov 2017

Dalton Trans., 2018,47, 654-658

Exploration of new water stable proton-conducting materials in an amino acid-templated metal phosphate system

J. Shi, K. Wang, J. Li, H. Zeng, Q. Zhang and Z. Lin, Dalton Trans., 2018, 47, 654 DOI: 10.1039/C7DT04125J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements