High-yield synthesis of a unique Mn(iii) siloxide complex through KMnO4 oxidation of a Mn(ii) precursor

Abstract

A unique trivalent manganese siloxide complex, blue-violet Mn^IIILi₂Cl[(Ph₂SiO)₂O]₂(THF)₄·2THF (3) has been prepared by a straightforward two-step synthetic protocol. Lithiation of (Ph₂SiOH)₂O (1) followed by reaction with MnCl₂(THF)₂ gave the structurally remarkable Mn(II) precursor Mn^IILi₄Cl₂[(Ph₂SiO)₂O]₂(THF)₅·2THF (2). Surprisingly, the final oxidation step could be achieved using KMnO₄ in THF to provide the Mn(III) species 3 in high yield (91%). Both title compounds were structurally characterized by single-crystal X-ray diffraction.