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Issue 7, 2018
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Trace level Al3+ detection in aqueous media utilizing luminescent ensembles comprising pyrene laced dynamic surfactant assembly

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Abstract

Easily synthesizable amphiphilic probes have been designed for the detection of Al3+ exclusively at mesoscopic interfaces. The surface charge of the surfactant assemblies and the fluidity of the lipid aggregates show pronounced effects on the extent of Al3+ detection. Excellent sensitivity has been observed specifically in the presence of anionic surfactants and the lipid membranes with more sol-like characteristics. Moreover, a variation in the modes of Al3+ complexation is observed on shifting from one regioisomer to another. For instance, the para isomer exhibits a 1 : 2 stoichiometry with the Al3+ ion, while for the ortho-isomer, it is a 1 : 1 interaction. Considering the excellent sensitivity of the probe molecule towards Al3+, the present system has been utilized for the estimation of soluble aluminum content in acidic soil samples as well as in pharmaceutical tablets. Low-cost paper strips are developed for rapid, on-site detection of Al3+ without involving advanced instruments or trained technicians. Finally, the bioimaging of Al3+ is achieved in cervical cancer (HeLa) cells.

Graphical abstract: Trace level Al3+ detection in aqueous media utilizing luminescent ensembles comprising pyrene laced dynamic surfactant assembly

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Supplementary files

Article information


Submitted
12 Sep 2017
Accepted
28 Nov 2017
First published
26 Jan 2018

Dalton Trans., 2018,47, 2352-2359
Article type
Paper

Trace level Al3+ detection in aqueous media utilizing luminescent ensembles comprising pyrene laced dynamic surfactant assembly

N. Dey and S. Bhattacharya, Dalton Trans., 2018, 47, 2352
DOI: 10.1039/C7DT03401F

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