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Issue 48, 2017
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Distinct room-temperature dielectric transition in a perchlorate-based organic–inorganic hybrid perovskite

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Abstract

The organic–inorganic hybrid perovskite (H2hpz)[K(ClO4)3] (H2hpz = diprotonated homopiperazine) exhibits a distinct room-temperature dielectric transition. The dielectric switching at 303 K is associated with an order–disorder transition of the polar guest cation confined in the cage, corresponding to a dynamic change between motional and frozen states.

Graphical abstract: Distinct room-temperature dielectric transition in a perchlorate-based organic–inorganic hybrid perovskite

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Article information


Submitted
10 Oct 2017
Accepted
07 Nov 2017
First published
07 Nov 2017

Dalton Trans., 2017,46, 16774-16778
Article type
Communication

Distinct room-temperature dielectric transition in a perchlorate-based organic–inorganic hybrid perovskite

Y. Sun, C. Shi and W. Zhang, Dalton Trans., 2017, 46, 16774
DOI: 10.1039/C7DT03798H

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