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Issue 43, 2017
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Silylene-assisted hydride transfer to CO2 and CS2 at a [P2Si]Ru pincer-type complex

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Abstract

The synthesis and characterization of base-stabilized and base-free pincer-type bis(phosphine)/silylene [P2Si]Ru complexes are reported. The base-free complex readily reduces CO2 and CS2via silylene-assisted hydride transfer, affording structurally distinct products with silicon-to-ruthenium formate and dithioformate bridges.

Graphical abstract: Silylene-assisted hydride transfer to CO2 and CS2 at a [P2Si]Ru pincer-type complex

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Publication details

The article was received on 28 Sep 2017, accepted on 13 Oct 2017 and first published on 20 Oct 2017


Article type: Communication
DOI: 10.1039/C7DT03659K
Dalton Trans., 2017,46, 14757-14761

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    Silylene-assisted hydride transfer to CO2 and CS2 at a [P2Si]Ru pincer-type complex

    M. T. Whited, J. Zhang, S. Ma, B. D. Nguyen and D. E. Janzen, Dalton Trans., 2017, 46, 14757
    DOI: 10.1039/C7DT03659K

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