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Issue 36, 2017
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Ring expansion of a ring expanded carbene

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Abstract

Reaction of phenylsilane with the ring expanded carbene 6-Mes results in facile Si–H oxidative addition to the carbenic carbon at room temperature. Heating the resultant diorganosilane product induces ring expansion through silicon to carbon migration of either the Si–H or Si–Ph bonds.

Graphical abstract: Ring expansion of a ring expanded carbene

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Supplementary files

Article information


Submitted
16 Aug 2017
Accepted
21 Aug 2017
First published
21 Aug 2017

This article is Open Access

Dalton Trans., 2017,46, 12015-12018
Article type
Communication

Ring expansion of a ring expanded carbene

L. García, K. H. M. Al Furaiji, D. J. D. Wilson, J. L. Dutton, M. S. Hill and M. F. Mahon, Dalton Trans., 2017, 46, 12015
DOI: 10.1039/C7DT03046K

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