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Issue 41, 2017
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A new Mo(iv) complex with the pentadentate (N3O2) Schiff-base ligand: the first non-cyanide pentagonal–bipyramidal paramagnetic 4d complex

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Abstract

A heptacoordinate complex [MoIV(DAPBH)Cl2] (H2DAPBH is 1,1′-(pyridine-2,6-diyl)bis(ethan-1-yl-1-ylidene)dibenzohydrazine) has been synthesized and characterized structurally and magnetically. It exhibits a slightly distorted pentagonal bipyramidal geometry and reveals paramagnetic behaviour resulting from two unpaired electrons (S = 1) with large positive zero-field splitting (D = +50 cm−1) and pronounced temperature-independent paramagnetism.

Graphical abstract: A new Mo(iv) complex with the pentadentate (N3O2) Schiff-base ligand: the first non-cyanide pentagonal–bipyramidal paramagnetic 4d complex

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Article information


Submitted
07 Aug 2017
Accepted
14 Sep 2017
First published
18 Sep 2017

Dalton Trans., 2017,46, 14083-14087
Article type
Communication

A new Mo(IV) complex with the pentadentate (N3O2) Schiff-base ligand: the first non-cyanide pentagonal–bipyramidal paramagnetic 4d complex

V. S. Mironov, T. A. Bazhenova, Yu. V. Manakin, K. A. Lyssenko, A. D. Talantsev and E. B. Yagubskii, Dalton Trans., 2017, 46, 14083
DOI: 10.1039/C7DT02912H

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