Issue 33, 2017
From the journal:

Dalton Transactions

Imidazolium cation transportation in a 1-D coordination polymer†

Wenqian Chen,a   Naoki Ogiwara,a   Kentaro Kadota,a   Kitt Panyarat,b   Susumu Kitagawa*c  and  Satoshi Horike ORCID logo *ac  

* Corresponding authors

a Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan

b Department of Chemistry, Faculty of Science, Chiang Mai University, Thailand

c Institute for Integrated Cell-Material Sciences, Institute for Advanced Study, Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan

Abstract

We synthesized a coordination polymer, [EtMeIm][Cu(bpy)(Me2PO4)3], containing an anionic 1-D chain and an ethyl methyl imidazolium cation. The organic cations show fast transport behavior, and the observed ion conductivity is 1.4 × 10−3 S cm−1 at 110 °C. The stability and structure of the material were confirmed by DSC, X-ray adsorption, and long-term AC impedance spectroscopy.

Graphical abstract: Imidazolium cation transportation in a 1-D coordination polymer

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Article information

DOI
https://doi.org/10.1039/C7DT02625K
Article type
Communication
Submitted
19 Jul 2017
Accepted
25 Jul 2017
First published
25 Jul 2017

Dalton Trans., 2017,46, 10798-10801

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Imidazolium cation transportation in a 1-D coordination polymer

W. Chen, N. Ogiwara, K. Kadota, K. Panyarat, S. Kitagawa and S. Horike, Dalton Trans., 2017, 46, 10798 DOI: 10.1039/C7DT02625K

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