Jump to main content
Jump to site search

Issue 36, 2017
Previous Article Next Article

Direct transformation of 2-acetylpyridine oxime esters into α-oxygenated imines in an Ir(iii) complex

Author affiliations

Abstract

2-Acetylpyridine oxime esters are transformed into the corresponding α-oxygenated imines in an Ir(III) complex under mild conditions, where the selective metal coordination of the imino group effectively promotes tautomerization of the oxime esters into the N-oxyenamines and the subsequent rearrangement.

Graphical abstract: Direct transformation of 2-acetylpyridine oxime esters into α-oxygenated imines in an Ir(iii) complex

Back to tab navigation

Supplementary files

Article information


Submitted
12 Jul 2017
Accepted
24 Aug 2017
First published
24 Aug 2017

Dalton Trans., 2017,46, 12032-12035
Article type
Communication

Direct transformation of 2-acetylpyridine oxime esters into α-oxygenated imines in an Ir(III) complex

H. Takahashi, S. Kodama and Y. Ishii, Dalton Trans., 2017, 46, 12032
DOI: 10.1039/C7DT02528A

Social activity

Search articles by author

Spotlight

Advertisements