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Issue 29, 2017
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Highlight on the solution processes occurring on silver(i)-assembling porphyrins in the presence of an excess of silver salt

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Abstract

Coordination cages obtained upon complexation of pyridyl functionalized porphyrins by Ag+ disassemble when overtaking a 1 : 2 stoichiometric amount of silver salt. An excess of Ag+ then leads to unusual chemical processes, here analyzed in detail, which permanently transform the monomeric porphyrins. The observed processes, discussed with reference to model compounds devoid of polyether substituted pyridyl residues, evidence a peculiar reactivity for meso 2,6-dimethylphenyl substituted porphyrins.

Graphical abstract: Highlight on the solution processes occurring on silver(i)-assembling porphyrins in the presence of an excess of silver salt

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Article information


Submitted
17 Mar 2017
Accepted
21 Jun 2017
First published
07 Jul 2017

Dalton Trans., 2017,46, 9375-9381
Article type
Paper

Highlight on the solution processes occurring on silver(I)-assembling porphyrins in the presence of an excess of silver salt

T. T. Dang, S. Durot, L. Monnereau, V. Heitz, A. Barbieri and B. Ventura, Dalton Trans., 2017, 46, 9375
DOI: 10.1039/C7DT00974G

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