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Issue 20, 2017
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First examples of tri- and tetraphosphametacyclophanes: synthesis and isolation of an unusual hexapalladium complex containing pincer units with Pd–P covalent bonds

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Abstract

The synthesis of the first examples of tri- and tetraphosphametacyclophanes [m-{–C(O)C5H3N(C(O)PPh)}3 (1) and m-{–C(O)C5H3N(C(O)PPh)}4 (2)] is described. The reaction of 1 with [Pd(η3-C3H5)Cl]2 yielded a rare hexapalladium(II) complex with four Pd–P covalent bonds.

Graphical abstract: First examples of tri- and tetraphosphametacyclophanes: synthesis and isolation of an unusual hexapalladium complex containing pincer units with Pd–P covalent bonds

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Article information


Submitted
28 Feb 2017
Accepted
20 Apr 2017
First published
21 Apr 2017

Dalton Trans., 2017,46, 6510-6513
Article type
Communication

First examples of tri- and tetraphosphametacyclophanes: synthesis and isolation of an unusual hexapalladium complex containing pincer units with Pd–P covalent bonds

V. S. Kashid, L. Radhakrishna and M. S. Balakrishna, Dalton Trans., 2017, 46, 6510
DOI: 10.1039/C7DT00737J

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