Issue 14, 2017
From the journal:

Dalton Transactions

Frustrated Lewis pair behavior of a neutral scandium complex†

Kejian Changa  and  Xin Xu ORCID logo *a  

* Corresponding authors

a Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. China
E-mail: xinxu@suda.edu.cn

Abstract

An easily-accessible neutral scandium complex Sc[OC(CH3)2CH2PPh2][O-2,6-tBu2-C6H3]2[THF] behaves as a reactive Sc/P frustrated Lewis pair, which when added to organic and inorganic substrates e.g. carbonyl compounds, transition-metal chlorides, and diazoalkane compounds, yields unique and intriguing addition products such as a Sc/Rh heterobimetallic complex and a Sc phosphazine complex.

Graphical abstract: Frustrated Lewis pair behavior of a neutral scandium complex

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C7DT00676D
Article type
Communication
Submitted
23 Feb 2017
Accepted
02 Mar 2017
First published
09 Mar 2017

Dalton Trans., 2017,46, 4514-4517

Permissions

Request permissions

Frustrated Lewis pair behavior of a neutral scandium complex

K. Chang and X. Xu, Dalton Trans., 2017, 46, 4514 DOI: 10.1039/C7DT00676D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements