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Issue 10, 2017
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Confined condensation synthesis and magnetic properties of layered copper hydroxide frameworks

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Abstract

We present a confined condensation technique for the fabrication of layered copper hydroxide frameworks from lamellar copper-organic assemblies with long alkyl chains through the selective introduction of hydroxo bridging ligands. The complete transformations of two different lamellar copper-organic assemblies, Cu(C12H25SO4)2·4H2O (Cu-DS) and Cu2(C11H23CO2)4·2H2O (Cu-lau), into the corresponding layered copper hydroxide frameworks, Cu2(OH)3(C12H25SO4) (Cu-OH-DS) and Cu2(OH)1.8(C11H23CO2)2.2 (Cu-OH-lau), were achieved via confined condensation. The magnetic properties of both lamellar copper-organic assemblies, Cu-DS and Cu-lau, and both layered copper hydroxide frameworks, Cu-OH-DS and Cu-OH-lau, were investigated. It was found that drastic changes in the magnetic properties arise as a result of the confined condensation process.

Graphical abstract: Confined condensation synthesis and magnetic properties of layered copper hydroxide frameworks

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Supplementary files

Article information


Submitted
09 Jan 2017
Accepted
17 Feb 2017
First published
17 Feb 2017

Dalton Trans., 2017,46, 3363-3368
Article type
Paper

Confined condensation synthesis and magnetic properties of layered copper hydroxide frameworks

S. Park, M. Jung, Y. Lee and Y. Huh, Dalton Trans., 2017, 46, 3363
DOI: 10.1039/C7DT00071E

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