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Issue 9, 2017
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Structural diversity of alkali-metal (Li, Na, K) alkyl zincates containing bidentate aminopyrrolyl ligands: from molecular complexes to coordination polymers

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Abstract

The exploration of co-complexation reactions between alkai-metal reagents and ZnEt2 with bidentate aminopyrrolyl ligands afforded a series of alkali-metal (Li, Na, K) alkyl zincates with a variety of intriguing structures, ranging from molecular complexes to more coordination polymers. All aforementioned complexes have been characterized by X-ray crystallography, NMR, IR and UV-vis spectroscopy.

Graphical abstract: Structural diversity of alkali-metal (Li, Na, K) alkyl zincates containing bidentate aminopyrrolyl ligands: from molecular complexes to coordination polymers

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Publication details

The article was received on 06 Jan 2017, accepted on 30 Jan 2017 and first published on 30 Jan 2017


Article type: Communication
DOI: 10.1039/C7DT00052A
Dalton Trans., 2017,46, 2765-2769

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    Structural diversity of alkali-metal (Li, Na, K) alkyl zincates containing bidentate aminopyrrolyl ligands: from molecular complexes to coordination polymers

    Z. Guo, Y. Wang, W. Cao, J. Chao and X. Wei, Dalton Trans., 2017, 46, 2765
    DOI: 10.1039/C7DT00052A

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