Jump to main content
Jump to site search

Issue 6, 2017
Previous Article Next Article

Molecular magnesium hydrides supported by an anionic triazacyclononane-type ligand

Author affiliations

Abstract

Molecular magnesium hydride with a terminal metal–hydrogen bond [Mg(iPr2TACN·AliBu3)H]2 supported by a monoanionic TACN-type ligand (TACN = 1,4-di-isopropyl-1,4,7-triazacyclononane) rearranges to form the dinuclear magnesium hydride [Mg(iPr2TACN·AlHiBu2)(μ-H)]2, exhibiting a rare Mg⋯H–Al interaction.

Graphical abstract: Molecular magnesium hydrides supported by an anionic triazacyclononane-type ligand

Back to tab navigation

Supplementary files

Publication details

The article was received on 09 Dec 2016, accepted on 11 Jan 2017 and first published on 11 Jan 2017


Article type: Communication
DOI: 10.1039/C6DT04654A
Citation: Dalton Trans., 2017,46, 1761-1765
  •   Request permissions

    Molecular magnesium hydrides supported by an anionic triazacyclononane-type ligand

    S. Schnitzler, P. Cui, T. P. Spaniol and J. Okuda, Dalton Trans., 2017, 46, 1761
    DOI: 10.1039/C6DT04654A

Search articles by author

Spotlight

Advertisements