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Issue 6, 2017
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Molecular magnesium hydrides supported by an anionic triazacyclononane-type ligand

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Abstract

Molecular magnesium hydride with a terminal metal–hydrogen bond [Mg(iPr2TACN·AliBu3)H]2 supported by a monoanionic TACN-type ligand (TACN = 1,4-di-isopropyl-1,4,7-triazacyclononane) rearranges to form the dinuclear magnesium hydride [Mg(iPr2TACN·AlHiBu2)(μ-H)]2, exhibiting a rare Mg⋯H–Al interaction.

Graphical abstract: Molecular magnesium hydrides supported by an anionic triazacyclononane-type ligand

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Publication details

The article was received on 09 Dec 2016, accepted on 11 Jan 2017 and first published on 11 Jan 2017


Article type: Communication
DOI: 10.1039/C6DT04654A
Citation: Dalton Trans., 2017,46, 1761-1765

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    Molecular magnesium hydrides supported by an anionic triazacyclononane-type ligand

    S. Schnitzler, P. Cui, T. P. Spaniol and J. Okuda, Dalton Trans., 2017, 46, 1761
    DOI: 10.1039/C6DT04654A

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