Issue 4, 2017
From the journal:

Dalton Transactions

Effects of Ru(ii/iii) redox on the Co(ii) coordination number and magnetic properties of 1D cyanide-bridged Co–Ru compounds†

Xiaoquan Zhu,ab   Shaodong Su,ab   Wenhai Cao,ab   Shengmin Hu,a   Yuehong Wen,a   Xintao Wua  and  Tianlu Sheng ORCID logo *a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, China
E-mail: tsheng@fjirsm.ac.cn

b School of Chemistry and Chemical Engineering, University of Chinese Academy of Sciences, Beijing, China

Abstract

A new 1D cyanide-bridged Co–Ru compound, {[trans-RuIII(dmap)4(CN)2Co(dipic)(MeOH)](PF6)}n (1a) (dmap = 4-dimethylaminopyridine, dipic = pyridine-2,6-dicarboxylate), and its reduced state, [trans-RuII(dmap)4(CN)2Co(dipic)]n (1b) have been synthesized. Upon the Ru center reduction from III to II, the MeOH solvent molecule bound to Co(II) in 1a is expelled. 1a displays ferrimagnetic properties but 1b is only a paramagnetic compound.

Graphical abstract: Effects of Ru(ii/iii) redox on the Co(ii) coordination number and magnetic properties of 1D cyanide-bridged Co–Ru compounds

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Article information

DOI
https://doi.org/10.1039/C6DT04397F
Article type
Communication
Submitted
19 Nov 2016
Accepted
13 Dec 2016
First published
13 Dec 2016

Dalton Trans., 2017,46, 1038-1041

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Effects of Ru(II/III) redox on the Co(II) coordination number and magnetic properties of 1D cyanide-bridged Co–Ru compounds

X. Zhu, S. Su, W. Cao, S. Hu, Y. Wen, X. Wu and T. Sheng, Dalton Trans., 2017, 46, 1038 DOI: 10.1039/C6DT04397F

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