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Issue 5, 2017
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{Fe3Nb25} cluster based on an Fe-centred Keggin unit

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Abstract

A new heteropolyniobate, [Fe3Nb25O76]18−, persists in aqueous solution by means of electrospray ionization mass spectrometry. It has been synthesized and characterized by IR, TGA, EDX-SEM, magnetic and single-crystal X-ray diffraction, and it features an Fe-centred Nb-Keggin unit {Fe3Nb10}.

Graphical abstract: {Fe3Nb25} cluster based on an Fe-centred Keggin unit

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Article information


Submitted
05 Nov 2016
Accepted
15 Dec 2016
First published
15 Dec 2016

Dalton Trans., 2017,46, 1368-1371
Article type
Communication

{Fe3Nb25} cluster based on an Fe-centred Keggin unit

Z. Liang, K. Wang, D. Zhang, P. Ma, J. Niu and J. Wang, Dalton Trans., 2017, 46, 1368
DOI: 10.1039/C6DT04223F

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