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Issue 12, 2017
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C–H⋯Cl hydrogen bonds in solution and in the solid-state: HgCl2 complexes with cyclen-based cryptands

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Abstract

Structural evidence is reported for C–H⋯Cl hydrogen bonds in solution and in the solid state of HgCl2 complexes with cyclen-based cryptands. These cyclen-based cryptands (1) and (2) are bridged by di- and triethylene glycol units, respectively, between two aromatic rings. The X-ray structure indicates that the 2/HgCl2 complex contains an acetonitrile molecule in the cavity.

Graphical abstract: C–H⋯Cl− hydrogen bonds in solution and in the solid-state: HgCl2 complexes with cyclen-based cryptands

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Supplementary files

Article information


Submitted
30 Aug 2016
Accepted
20 Jan 2017
First published
20 Jan 2017

Dalton Trans., 2017,46, 3800-3804
Article type
Communication

C–H⋯Cl hydrogen bonds in solution and in the solid-state: HgCl2 complexes with cyclen-based cryptands

M. Ikeda, A. K. Sah, M. Iwase, R. Murashige, J. Ishi-i, M. Hasegawa, C. Kachi-Terajima, K. Park, S. Kuwahara and Y. Habata, Dalton Trans., 2017, 46, 3800
DOI: 10.1039/C6DT03390C

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