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Issue 42, 2016
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Water-dependent charge-transfer-induced spin transition of Prussian blue analogues

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Abstract

Cobalt–iron Prussian blue analogues are magnetic functional compounds that exhibit charge-transfer-induced spin transition (CTIST), however, the role of guest species such as water in influencing the magnetic behaviour has remained unclear. Here, we report the water-dependent CTIST behaviour of Na0.46Co[Fe(CN)6]0.78(H2O)1.31 together with its single crystal X-ray structural analysis, for the first time.

Graphical abstract: Water-dependent charge-transfer-induced spin transition of Prussian blue analogues

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Supplementary files

Article information


Submitted
06 Sep 2016
Accepted
29 Sep 2016
First published
30 Sep 2016

Dalton Trans., 2016,45, 16784-16788
Article type
Communication

Water-dependent charge-transfer-induced spin transition of Prussian blue analogues

H. Ohmagari, R. Ohtani, M. Nakaya, M. Ohba, M. Nakamura, L. F. Lindoy, O. Sato and S. Hayami, Dalton Trans., 2016, 45, 16784 DOI: 10.1039/C6DT03474H

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