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Issue 43, 2016
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A nonlinear optical active polymer film based on Pd(ii) dithione/dithiolate second-order NLO chromophores

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Abstract

A film of [Pd(R2pipdt)(dmit)] (1), where R2pipdt = 1,4-didodecyl-piperazine-2,3-dithione (acceptor) and dmit = 2-thioxo-1,3-dithiole-4,5-dithiolate (donor) incorporated into a polymethylmethacrylate (PMMA) matrix, showing a good second-harmonic generation, has been prepared for the first time in the class of dithione–dithiolate 2nd order NLO-chromophores. Moreover full characterization of 1, including molecular second-order NLO properties in solution, is reported.

Graphical abstract: A nonlinear optical active polymer film based on Pd(ii) dithione/dithiolate second-order NLO chromophores

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Supplementary files

Article information


Submitted
22 Jul 2016
Accepted
28 Sep 2016
First published
28 Sep 2016

Dalton Trans., 2016,45, 17431-17438
Article type
Paper

A nonlinear optical active polymer film based on Pd(II) dithione/dithiolate second-order NLO chromophores

D. Espa, L. Pilia, L. Marchiò, F. Artizzu, G. Di Carlo, D. Marinotto, A. Serpe, F. Tessore and P. Deplano, Dalton Trans., 2016, 45, 17431
DOI: 10.1039/C6DT02911F

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