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Issue 31, 2016
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Self-assembly of highly luminescent heteronuclear coordination cages

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Abstract

Exo-functionalized Pd2L4 cage compounds with attached Ru(II) pyridine complexes were prepared via coordination-driven self-assembly. Unlike most of the previously reported palladium(II) cages, one of these metallocages exhibits an exceptionally high quantum yield of 66%. The presented approach is promising to obtain luminescent coordination complexes for various applications.

Graphical abstract: Self-assembly of highly luminescent heteronuclear coordination cages

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Supplementary files

Article information


Submitted
08 Jul 2016
Accepted
12 Jul 2016
First published
12 Jul 2016

This article is Open Access

Dalton Trans., 2016,45, 12297-12300
Article type
Communication

Self-assembly of highly luminescent heteronuclear coordination cages

A. Schmidt, M. Hollering, J. Han, A. Casini and F. E. Kühn, Dalton Trans., 2016, 45, 12297
DOI: 10.1039/C6DT02708C

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