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Issue 41, 2016
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Counterion-dominating chirality transfer between chiral and achiral polyoxometalates

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Abstract

We show that chirality transfer from chiral polyoxometalates to achiral polyoxometalates can occur in aqueous solution with unexpected selectivity of surrounding counterions. In comparison with sodium ions, protonated dimethylammonium counterions play a critical role in shortening the inter-cluster distance, thus promoting the efficiency of chirality transfer.

Graphical abstract: Counterion-dominating chirality transfer between chiral and achiral polyoxometalates

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Publication details

The article was received on 27 Jun 2016, accepted on 13 Sep 2016 and first published on 14 Sep 2016


Article type: Communication
DOI: 10.1039/C6DT02564A
Dalton Trans., 2016,45, 16139-16143

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    Counterion-dominating chirality transfer between chiral and achiral polyoxometalates

    L. Shi, F. Jiang, B. Li and L. Wu, Dalton Trans., 2016, 45, 16139
    DOI: 10.1039/C6DT02564A

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