Issue 36, 2016

Thiazolylimines as novel ligand-systems for spin-crossover centred near room temperature

Abstract

A new thiazolylimine ligand system for iron(II) complexes which stabilises spin-crossover in solution and solid states with T1/2 temperatures around room temperature has been developed. This effect is studied in solution and solid states. Furthermore crystal packing effects are investigated offering a variety of T1/2 and even hysteresis centred at −3 °C in the solid state.

Graphical abstract: Thiazolylimines as novel ligand-systems for spin-crossover centred near room temperature

Supplementary files

Article information

Article type
Communication
Submitted
24 May 2016
Accepted
10 Aug 2016
First published
10 Aug 2016

Dalton Trans., 2016,45, 14023-14029

Thiazolylimines as novel ligand-systems for spin-crossover centred near room temperature

N. Struch, N. Wagner, G. Schnakenburg, R. Weisbarth, S. Klos, J. Beck and A. Lützen, Dalton Trans., 2016, 45, 14023 DOI: 10.1039/C6DT02077A

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