Issue 16, 2016

Highly efficient and reusable CNT supported iron(ii) catalyst for microwave assisted alcohol oxidation

Abstract

The highly efficient eco-friendly synthesis of ketones (yields over 99%) from secondary alcohols is achieved by combination of [FeCl23-HC(pz)3}] (pz = pyrazol-1-yl) supported on functionalized multi-walled carbon nanotubes and microwave irradiation, in a solvent-free medium. The carbon homoscorpionate iron(II) complex is the first one of this class to be used as catalyst for the oxidation of alcohols.

Graphical abstract: Highly efficient and reusable CNT supported iron(ii) catalyst for microwave assisted alcohol oxidation

Supplementary files

Article information

Article type
Communication
Submitted
04 Feb 2016
Accepted
16 Mar 2016
First published
16 Mar 2016

Dalton Trans., 2016,45, 6816-6819

Highly efficient and reusable CNT supported iron(II) catalyst for microwave assisted alcohol oxidation

L. M. D. R. S. Martins, A. P. C. Ribeiro, S. A. C. Carabineiro, J. L. Figueiredo and A. J. L. Pombeiro, Dalton Trans., 2016, 45, 6816 DOI: 10.1039/C6DT00514D

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