Issue 7, 2016
From the journal:

Dalton Transactions

Homoleptic octahedral coordination of CH3CN to Mg2+ in the Mg[N(SO2CF3)2]2–CH3CN system†

Gleb Veryasov,a   Kazuhiko Matsumoto*a  and  Rika Hagiwara*a  

* Corresponding authors

a Department of Fundamental Energy Science, Graduate School of Energy Science, Kyoto University, Sakyo-ku, Kyoto 606-8501, Japan
E-mail: k-matsumoto@energy.kyoto-u.ac.jp, hagiwara@energy.kyoto-u.ac.jp
Tel: +8175-753-5827

Abstract

X-ray diffraction and Raman spectroscopic measurements revealed a homoleptic octahedral coordination of CH3CN to Mg2+ in the [Mg(CH3CN)6][TFSA]2 (TFSA = bis(trifluoromethylsulfonyl)imide) crystal structure and in Mg[TFSA]2/CH3CN electrolytes.

Graphical abstract: Homoleptic octahedral coordination of CH3CN to Mg2+ in the Mg[N(SO2CF3)2]2–CH3CN system

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Article information

DOI
https://doi.org/10.1039/C5DT04821D
Article type
Communication
Submitted
10 Dec 2015
Accepted
15 Jan 2016
First published
15 Jan 2016

Dalton Trans., 2016,45, 2810-2813

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Homoleptic octahedral coordination of CH3CN to Mg2+ in the Mg[N(SO2CF3)2]2–CH3CN system

G. Veryasov, K. Matsumoto and R. Hagiwara, Dalton Trans., 2016, 45, 2810 DOI: 10.1039/C5DT04821D

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