Jump to main content
Jump to site search

Issue 6, 2016
Previous Article Next Article

White phosphorus activation by a Th(iii) complex

Author affiliations

Abstract

[Th(Cp′′)3] (Cp′′ = {C5H3(SiMe3)2-1,3}) activates P4 to give [{Th(Cp′′)3}2(μ–η11-P4)] (1), which has an unprecedented cyclo-P4 binding mode. DFT studies were performed on a model of 1 to probe the bonding in this system.

Graphical abstract: White phosphorus activation by a Th(iii) complex

Back to tab navigation

Supplementary files

Article information


Submitted
17 Nov 2015
Accepted
06 Jan 2016
First published
06 Jan 2016

This article is Open Access

Dalton Trans., 2016,45, 2390-2393
Article type
Communication
Author version available

White phosphorus activation by a Th(III) complex

A. Formanuik, F. Ortu, R. Beekmeyer, A. Kerridge, R. W. Adams and D. P. Mills, Dalton Trans., 2016, 45, 2390 DOI: 10.1039/C5DT04528B

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Read more about how to correctly acknowledge RSC content.


Social activity

Search articles by author

Spotlight

Advertisements