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Issue 3, 2016
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Bimetallic nickel complexes for selective CO2 carbon capture and sequestration

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Abstract

Herein we report a dinickel azacryptand complex that enables fast, selective, and tight CO2 binding from air. Exploiting the affinity of the cavitand towards azides, CO2 release was observed. Despite the stability of the azido complex, UV irradiation under atmospheric conditions proved to be a suitable pathway for N3 replacement by CO2.

Graphical abstract: Bimetallic nickel complexes for selective CO2 carbon capture and sequestration

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Supplementary files

Article information


Submitted
30 Oct 2015
Accepted
08 Dec 2015
First published
09 Dec 2015

This article is Open Access

Dalton Trans., 2016,45, 904-907
Article type
Communication
Author version available

Bimetallic nickel complexes for selective CO2 carbon capture and sequestration

F. Möller, K. Merz, C. Herrmann and U.-P. Apfel, Dalton Trans., 2016, 45, 904
DOI: 10.1039/C5DT04267D

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