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Issue 3, 2016
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Surprising coordination for low-valent actinides resembling uranyl(vi) in thorium(iv) organic hybrid layered and framework structures based on a graphene-like (6,3) sheet topology

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Abstract

Three thorium(IV)-based metal–organic hybrid compounds with 2D layered and 3D framework structures exhibiting graphene-like (6,3) sheet topologies were prepared with linkers with threefold symmetry. These compounds contain rare and relatively anisotropic coordination environments for low-valent actinides that are similar to those often observed for high-valent actinide ions.

Graphical abstract: Surprising coordination for low-valent actinides resembling uranyl(vi) in thorium(iv) organic hybrid layered and framework structures based on a graphene-like (6,3) sheet topology

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The article was received on 24 Oct 2015, accepted on 04 Dec 2015 and first published on 07 Dec 2015


Article type: Communication
DOI: 10.1039/C5DT04183J
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Dalton Trans., 2016,45, 918-921

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    Surprising coordination for low-valent actinides resembling uranyl(VI) in thorium(IV) organic hybrid layered and framework structures based on a graphene-like (6,3) sheet topology

    Y. Li, Z. Weng, Y. Wang, L. Chen, D. Sheng, J. Diwu, Z. Chai, T. E. Albrecht-Schmitt and S. Wang, Dalton Trans., 2016, 45, 918
    DOI: 10.1039/C5DT04183J

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