Issue 2, 2016
From the journal:

Dalton Transactions

Nickel(ii) complexes of N-CH2CF3 cyclam derivatives as contrast agents for 19F magnetic resonance imaging†

Jan Blahut,a   Petr Hermann,a   Andrea Gálisová,b   Vít Herynek,b   Ivana Císařová,a   Zdeněk Tošnerc  and  Jan Kotek*a  

* Corresponding authors

a Department of Inorganic Chemistry, Faculty of Science, Charles University (Univerzita Karlova), Hlavova 2030, 128 43 Prague 2, Czech Republic
E-mail: modrej@natur.cuni.cz
Fax: +420-221951253
Tel: +420-221951261

b Department of Radiodiagnostic and Interventional Radiology, Magnetic Resonance Unit, Institute for Clinical and Experimental Medicine, Vídeňská 1958/9, Prague 4, 140 21 Czech Republic

c NMR Laboratory, Faculty of Science, Charles University (Univerzita Karlova), Hlavova 2030, 128 43 Prague 2, Czech Republic

Abstract

Kinetically inert Ni(II) complexes of N1,N8-bis(2,2,2-trifluoroethyl)cyclams with hydrogen atoms or phosphonic acid groups in the N4,N11-positions show significant 19F NMR relaxation rate enhancement useful for 19-fluorine MRI imaging.

Graphical abstract: Nickel(ii) complexes of N-CH2CF3 cyclam derivatives as contrast agents for 19F magnetic resonance imaging

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Article information

DOI
https://doi.org/10.1039/C5DT04138D
Article type
Communication
Submitted
21 Oct 2015
Accepted
18 Nov 2015
First published
20 Nov 2015
This article is Open Access
Creative Commons BY license

Dalton Trans., 2016,45, 474-478

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Nickel(II) complexes of N-CH2CF3 cyclam derivatives as contrast agents for 19F magnetic resonance imaging

J. Blahut, P. Hermann, A. Gálisová, V. Herynek, I. Císařová, Z. Tošner and J. Kotek, Dalton Trans., 2016, 45, 474 DOI: 10.1039/C5DT04138D

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