Issue 2, 2016

New mechanistic insight into intramolecular arene hydroxylation initiated by (μ-1,2-peroxo)diiron(iii) complexes with dinucleating ligands

Abstract

(μ-1,2-Peroxo)diiron(III) complexes (2-R) with dinucleating ligands (R-L) generated from the reaction of bis(μ-hydroxo)diiron(II) complexes [Fe2(R-L)(OH)2]2+ (1-R) with dioxygen in acetone at −20 °C provide a diiron-centred electrophilic oxidant, presumably diiron(IV)-oxo species, which is involved in aromatic ligand hydroxylation.

Graphical abstract: New mechanistic insight into intramolecular arene hydroxylation initiated by (μ-1,2-peroxo)diiron(iii) complexes with dinucleating ligands

Supplementary files

Article information

Article type
Communication
Submitted
19 Oct 2015
Accepted
23 Nov 2015
First published
23 Nov 2015

Dalton Trans., 2016,45, 469-473

Author version available

New mechanistic insight into intramolecular arene hydroxylation initiated by (μ-1,2-peroxo)diiron(III) complexes with dinucleating ligands

M. Sekino, H. Furutachi, K. Tasaki, T. Ishikawa, S. Mori, S. Fujinami, S. Akine, Y. Sakata, T. Nomura, T. Ogura, T. Kitagawa and M. Suzuki, Dalton Trans., 2016, 45, 469 DOI: 10.1039/C5DT04088D

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